No you are not understanding. The odds of any number being rolled on each individual dice throw is static. It makes no odds how many times you roll. The chances of you getting a particular number are the same on every throw.
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Yeah, they are the same on each throw I'm not saying it's 1/6 on first and 1/36 on second, it's 1/36 for both together. It's like flipping two coins at once, 1/2 chance to get heads on each, but 1/4 to get heads on both