I recently bought the Mask of the Third Man for my female human hunter from Xur in the tower this past weekend on 11-7-14. Shortly after buying the helmet I realized that the armor piece is not affected at all by any of the armor shaders. One change I often notice on other players is how the helmet turns white and the helmet's eyes change blue when you apply the Chatterwhite armor shader. When I do the same, the helmet remains black/gold with green eyes, as it does with every other shader I have. I don't know what's causing this and I can't seem to fix it, a solution would be greatly appreciated!
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Female hunters have green 'eyes' on that helmet. Male hunters have blue. It doesn't have anything to do with the shader equipped. Shaders don't affect most exotic equipment. You have to find a shader that compliments the piece in question.