Title explains the issue, really. it's not just visual either. The Unstoppable icon doesn't light up on the character sheet or appear in-game by the weapon icon (bottom-left), and it didn't Stun champions in the nightfall. Everything seems fine on other exotics and legendaries, although i didn't test all of them. My guess is that it's cuz it also jolts/overloads with an ionic trace, so something's not letting it double up.
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because you probably picked up an ionic trace that gives the weapon volt (or in other words "overload") You can only have one champion mod active at a time, and the perk of the weapon itself comes before the artifact