Decided to try to get my Polaris Lance's catalyst complete, with only needing 39 more perfect fifth kills. While I was in the Forfeit Shrine Ascendant Challenge activity, no matter how many precision hits/kills I got, I could never get the perfect fifth trait/perk to proc. I found a spot that attracts several Taken mobs and get easy precision kills. There is a slight pause when I fire, but it is usually less than a second.
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Hey, Do you mean the explosion isn't happening or that the kills aren't giving progress toward the catalyst? If it's the second, there is an error in the description given. You need to kill enemies with the burn after the Perfect Fifth explosion, not with the explosion itself. If it's the first, could you provide a video showing this. You can upload it to a public sharing site like YouTube and just post the link here.