From what I gather hitting someone with a headshot while getting flinched requires a couple things: patience, cool nerves & a little aim assist couldn't hurt. I've yet to master this, but I'm wondering what are some techniques snipers use to help develop this. At first I thought maybe I could work on this in pve but I think this only helps to a certain extent due to the stress factor being higher in Pvp. I'll look forward to your feedback!
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Unfortunately since the 2.4.0 patch, it's almost impossible to get a headshot while being flinched, even with good timing. If someone starts flinching you, your best bet is to switch to your primary. https://www.youtube.com/watch?v=aVo4z03aeaI