I think I discarded the first one I recieved, I found a few more but is the quest unavailable to my character since I made that mistake a few months ago? I discarded it because I had no clue what it was for and didn't realize stuff like it was important in this kind of game.
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Yes, you will be able to continue to collect the DVALIN relics as random loot drops from defeated enemies. Best of luck, Guardian!
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No worries. Those relics will always be dropping on characters that haven't collected them. If you haven't found one in a while, chances are you've already collected them. "The First Firewall" is your next step. This quest will appear in your Directory if you've given all four relics to Banshee, and will only appear on the 7th of every month.