I've finished the game before with Krieg and got to say it was pretty fun. I've yet to play the other characters but honestly I probably won't play as either Axton or Salvador anytime soon.
I just got the Handsome Collection and not sure which of the 4 (ik there's 6) characters to play as this time.
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Out of all the people i've played with the hardest for people to play properly is Maya. I've seen a lot of people playing her but very few getting it right. She's built for elemental damage yet I see so many people going for pure damage weapons over elemental. Hardest for me was Krieg. I played Maya for so long I struggled with an entirely different playstyle to what I was used to. Took me a lot longer than it should have done to get it right.