I consider myself a decent sniper, but when I go into Crucible, I'm wrecked beyond belief. There are guys who headshot me the very second they scope in. It's -blam!-ing ridiculous! I don't understand how they do it!
EDIT: A lot of people are saying that they get their skill from Halo. However, I actually snipe very well in Halo, but not-so-well in Destiny.
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I always found it best to never hesitate in taking a shot. When I think to hard I suck really bad. I try to get my daddy and mind into a relaxed state that dosnt care. When I hit that state of mind al shots and quick reaction come naturally. That's just me and what I found that does best. hope it might help.